We provide an elementary proof that, in a (transversely) unimodular contact Lie algebra, the adjoint action of the Reeb vector is nilpotent except when the Lie algebra is isomorphic to either or . We introduce a class of contact Lie algebras, called , containing all K-contact Lie algebras, and deduce from the previous result that the only centerless unimodular examples in this class are precisely and . This gives an alternative proof of the previously known fact that centerless unimodular Sasakian Lie algebras are isomorphic to either or . Some other results known to hold for Sasakian Lie algebras are generalized as well. We investigate several properties of DS-contact Lie algebras in relation to Frobenius Lie algebras, and also classify them in dimension five. Some implications for the contact Lefschetz condition are explored.

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