Gravitational-wave (GW) signals from compact binary coalescences (CBCs) enable independent measurements of the Hubble constant via the spectral siren method, which critically depends on an accurate model of the source-frame mass distribution. While the primary mass function has been extensively studied, the impact of the secondary mass distribution on cosmological inference has been largely overlooked. Here, we perform a joint inference of population and cosmological parameters using 142 confident CBC detections from GWTC-4.0, adopting a new parametric model that flexibly describes features in both the component-mass spectrum and the pairing function, with particular emphasis on the secondary masses. We find (68% CL) from spectral sirens alone, and when combined with the bright siren GW170817. Compared to the standard LVK Fullpop-4.0 analysis, these constraints represent improvements of and in uncertainty, respectively. The enhanced precision is driven by previously unmodeled features, including peaks near and as well as mass-dependent pairing transitions at and . Our results demonstrate that the secondary mass function is also a key ingredient for precision standard siren cosmology.

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