The single-ionization rate coefficient of a plasma neutral depends both on the microscopic electron-impact cross section and on the macroscopic shape of the electron energy distribution function (EEDF). We present a reproducible benchmark and sensitivity study – not a new theory – of these two effects for the three lightest neutrals He, Li, and Be, combining the recommended Bell~\ (1983) cross sections with a properly normalized two-temperature Tsallis -generalized EEDF and varying on both sides of the Maxwellian limit and the hot-electron fraction at . The calculation cleanly separates two independent uncertainty axes – cross-section model (Bell vs.\ Lotz) and EEDF shape (Maxwellian vs.\ Tsallis). The Bell–Lotz spread on is small for He (within about ), moderate for Be (), and largest for Li (up to at ~keV); sub-extensive distributions () suppress ionization through a hard tail cut-off, while super-extensive distributions () enhance low-temperature ionization through a -like power-law tail with . The quantitatively safest non-Maxwellian cases are and (), which lie inside the finite-mean-energy regime; the cases and are retained as heavy-tail stress tests and should be read as qualitative trends rather than as quantitatively reliable predictions. Both EEDF effects scale with , so He responds most strongly and Li least. The full numerical pipeline is released as a persistent reproducibility package, intended as a drop-in non-Maxwellian ionization module for collisional-radiative and ionization-balance modelling of light-neutral plasmas.

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