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We study conic divisorial ideals from the viewpoint of matroid theory and apply the resulting framework to toric rings arising from root systems. For a toric ring, we describe the polytope representing divisor classes corresponding to conic divisorial ideals in terms of matroids. We then turn to the toric ring associated with a certain subset of a classical root system, called a signed poset. We compute the divisor class group and characterize the (-)Gorenstein property of in terms of . Moreover, we also construct a polytope characterizing the conic divisorial ideals of . This recovers and extends previous results on Hibi rings to our toric rings.

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