We study entropy–coherence relations near rank-deficient support boundaries in finite-dimensional quantum systems. For block-diagonal reference states, we establish support-sensitive coercivity estimates showing that the entropy cost of cross-boundary coherence acquires a logarithmic enhancement as the population scale approaches the support boundary. Combined with finite-time entropy bounds, these estimates yield conditional entropy–activation bounds with a logarithmic correction factor of order in coherence-dominant regimes. The analysis proceeds through pinching reductions and effective Bogoliubov–Kubo–Mori (BKM) estimates adapted to the coherence–population structure. We further apply the framework to Davies semigroups under additional secular decoupling and population-rate assumptions. The resulting statements provide conditional certification bounds near rank-deficient stationary states, rather than general mixing-time or convergence-rate estimates.

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