The kink observed in the nuclear charge radius of Sn isotopes around neutron number is investigated within the relativistic mean-field (RMF) framework using the NL3 parameter set. It is shown that the small components of the Dirac spinors for the neutron single-particle states near the Fermi level play a crucial role in forming the kink through their contribution to the proton central potential. In particular, the significant differences between the radial parts of the small components of spin-orbit partner states make neutrons with more efficient in increasing the nuclear charge radius than those with . However, the effect induced by the small components alone does not fully account for the magnitude of the kink observed in Sn isotopes.

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