We report the first unambiguous detection of cannabinoid molecules in an exoplanetary atmosphere. Using 420 hours of JWST observations combining NIRSpec and MIRI instruments, we identify spectroscopic signatures of tetrahydrocannabinol (THC; -CHO) and cannabidiol (CBD; CHO) in the transmission spectrum of the temperate sub-Neptune K2-18b. The THC feature at 2.42~m is detected at 9.2 significance, while CBD absorption at 3.69~m reaches 7.8. We additionally report a mysterious feature at exactly 4.20~m detected at 4.20 (the probability of this coincidence is discussed extensively). Our atmospheric retrievals using the novel code indicate a CBD-to-THC ratio of 0.400.08, classifying K2-18b as a balanced hybrid'' world according to standard terrestrial cannabis taxonomy. We introduce the Cannabis Habitable Zone (Green Zone’‘) framework and demonstrate that K2-18b lies squarely within it. We explore multiple production mechanisms including biogenic synthesis, abiotic photochemistry, exogenous delivery via ``space nuggets,’’ and deliberate atmospheric engineering by an advanced civilization. These findings suggest that K2-18b may host conditions suitable for advanced photochemistry, atmospheric relaxation processes, and possibly the most chill civilization in the galaxy. If confirmed by independent observations, this represents a paradigm shift in our understanding of biosignatures and the prevalence of recreational organic chemistry in the cosmos.

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