Map-space / decompositions of linear polarization are attractive for foreground and CMB analyses because they isolate the -family patterns that contaminate primordial tensor searches from -family patterns that trace coherent Galactic structures. However, the / transform is non-fully-local and induces apparent spectral complexity in projected fields even when the underlying sky is spectrally simple in . We quantify this effect for synchrotron emission. We introduce a complex-parameter description of the frequency dependence of , its spin-preserving projections and , and the scalar , using complex log–Taylor and moment expansions (with simple transformation rules under / projection) and linking their coefficients to spectral-index variations, line-of-sight mixing, synchrotron ageing, and Faraday effects. Using a toy model and a PySM template, we find that scalar combinations, especially and , acquire the largest induced complexity, while is less affected but lacks a directly interpretable amplitude and angle. By contrast, and retain a clear geometric meaning and exhibit only moderate spectral distortions, while satisfying the closure relation (which extends to all spectral orders in the moment formalism). Finally, with three frequency channels, we compare low-order spectral truncations and propose diagnostics to test whether the data favour a single power law in or independent power laws in . This work is intended to be of practical relevance for both Galactic science and CMB -mode analyses and lays the conceptual foundation for a series of papers applying the framework to observational data.

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