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We develop the theory of Nekovář’s Selmer complexes. We prove that, under mild hypotheses, Nekovář’s Selmer complexes are canonically quasi-isomorphic to Poitou-Tate complexes", which arise from Poitou-Tate global duality exact sequences. We give two applications. Firstly, we prove that the determinant of a Selmer complex is canonically isomorphic to the module of Stark systems and, by using this result, we construct a canonical Heegner point Stark system" which controls Selmer groups. Secondly, we prove that the derived -adic height pairing of Bertolini-Darmon concides with that of Nekovář.

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