In this paper, we are interested in the existence and asymptotic behavior of least energy solutions to the upper critical Choquard equation \begin{equation*} \begin{cases} -Δu+au=\displaystyle\left(\int_Ω\frac{u^{6-α}(y)}{|x-y|^α}dy\right)u^{5-α}&\mbox{in}\ Ω, u>0 \ \ &\mbox{in}\ Ω, u=0 \ \ &\mbox{on}\ \partial Ω, \end{cases} \end{equation*} where is a bounded domain with a boundary, , , and the operator is coercive. We first establish that the following three properties are equivalent: the existence of least energy solutions, the validity of a strict inequality in the associated minimization problem, and the positivity of the Robin function somewhere in the domain. This leads naturally to the definition of a critical function . Under the perturbation with critical and , we prove that least energy solutions exist. Furthermore, we establish a refined energy estimate and describe their asymptotic profile.

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