In this paper, we consider the existence of positive solutions to the following slightly supercritical Choquard equation \begin{equation*} \begin{cases} -Δu=\displaystyle\Big(\int\limits_Ω\frac{u^{2^_α+\varepsilon}(y)}{|x-y|^α}dy\Big)u^{2^_α-1+\varepsilon},\quad u>0\ \ &\mbox{in}\ Ω, \quad \ \ u=0 \ \ &\mbox{on}\ \partial Ω, \end{cases} \end{equation*} where , is a smooth bounded domain in , , is the upper critical exponent in the sense of Hardy-Littlewood-Sobolev inequality and is a small parameter. In contrast with the slightly subcritical Choquard equation studied by Chen and Wang (Calculus of Variations and Partial Differential Equations, 63:235, 2024), we find that there is no chance to construct a family of single-bubble solutions as .

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