Refining hydrogen positions in α-FeOOH through combined neutron diffraction and computational techniques

The hydrogen positions and magnetic structure of goethite $\alpha$-FeOOH, a key component of iron rust, were examined through neutron diffraction. All symmetry-allowed magnetic structures under the space group $Pnma$ with the magnetic wavevector ${\vec{q}}_{\mathrm{m}}=(0,0,0)$ r.l.u. were analysed using irreducible representation and magnetic space group approaches. The magnetic moments aligned along the $b$-axis form antiferromagnetic spin arrangements, as reproduced by first-principles calculations. Accurately determining the hydrogen positions is crucial for understanding the mechanism of catalytic reduction of CO${}_2$ in $\alpha$-FeOOH. These positions were precisely identified through diffraction and calculations, highlighting the effectiveness of using both methods for undeuterated compounds.