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In this study, we present a novel family of exact black hole solutions constructed in the context of five-dimensional Gauss-Bonnet gravity. These solutions add a non-linear charge to the Bañados-Teitelboim-Zanelli-like configurations known to exist with arbitrary Thurston horizon geometry. We establish constraints on the parameter space defining physically viable black holes, aligning with the standard energy conditions. An explicit proof of the first law of thermodynamics within our scenario is provided. We also employ holographic techniques to characterize the DC conductivities for the distinct horizon geometries, identifying a critical temperature indicative of phase transitions and exploring pertinent limits.

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