X-ray binaries (XRBs) are unique laboratories where accretion, jets, strong gravity and magnetic fields can be probed on humanly tractable timescales. The phased SKA-Mid operating as a single, ultra-sensitive Very Long Baseline Interferometry (VLBI) element will transform radio studies of XRBs primarily through its time-domain capabilities: substantially improved sensitivity on VLBI baselines that include SKA-Mid in Bands 2 and 5, together with connected-element SKA-Mid imaging extending down to 0.35–1 GHz (Band 1), microarcsecond-precision astrometry for bright systems, high-fidelity polarimetry for the most strongly polarized sources, and rapid target-of-opportunity response. In synergy with global VLBI networks, SKA+VLBI will track the evolution of compact ejecta and compact jets on astronomical unit (AU) scales, measure frequency-dependent core shifts to infer magnetic field strengths and gradients, resolve disk–jet coupling during state transitions in real time, and determine precise distances and natal kicks via parallaxes and proper motions. Joint campaigns with future X-ray and optical telescopes will enable strictly simultaneous, multi-band constraints on accretion–ejection physics and on jet composition. We outline a quantitative program for \aastar\ and AA4, including cadenced, multi-frequency VLBI ``movies’’ of jets over the first days of outbursts, an XRB astrometric census, and a core-shift survey, and we provide representative detection rates, magnetic field measurements and distance accuracies. These outcomes will set the microphysical foundation for jet physics across the mass scale from stellar-mass black holes and neutron stars to active galactic nuclei, and will establish SKA+VLBI as the definitive facility for time-domain, high-resolution XRB astrophysics.

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