In this paper, we extend Stein’s method to the symmetric matrix normal distribution. In particular, we obtain a Stein characterization of the symmetric matrix normal distribution involving the extended generator of the symmetric matrix Ornstein-Uhlenbeck process, present a semigroup representation of the solution of the corresponding Stein equation, and establish regularity estimates for the solution. This framework of Stein’s method for symmetric matrix normal approximation complements the recent theory of Stein’s method for matrix normal approximation, and we make an explicit connection between these frameworks. We apply this theory to derive a Wasserstein distance bound for the symmetric matrix normal approximation of the Wishart distribution.

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