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We study refined asymptotics of scalar-flat ALE four-manifolds in the Tian–Viaclovsky setting, namely for self-dual or anti-self-dual metrics and for metrics with harmonic curvature. Starting from the ALE coordinates obtained by Tian–Viaclovsky, we construct preferred coordinates at infinity and identify the homogeneous term in the metric expansion. This term splits canonically into a scalar part determined by the ALE ADM mass and an algebraic Weyl tensor at infinity. As an application, we consider scalar-flat Kähler ALE metrics on minimal resolutions of quotient surface singularities. In this case, the leading Weyl tensor at infinity vanishes exactly when the minimal resolution is crepant.

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