We study doppelsemigroups, i.e., algebraic structures equip-ped with two associative binary operations satisfying a specified system of axioms. We investigate duality and isomorphisms of doppelsemigroups and examine the relationships between commutative, abelian, strong, and rectangular doppelsemigroups. Several examples are constructed, including nontrivial iso-opposite doppelsemigroups, noncommutative iso-dual doppelsemigroups, nonabelian iso-cross-dual doppelsemigroups, and nonstrong rectangular iso-opposite doppelsemigroups. Furthermore, we refine the complete classification of nonisomorphic doppelsemigroups of order~3. Finally, we present computer-assisted calculations yielding the numbers of all pairwise nonisomorphic doppelsemigroups and strong doppelsemigroups of orders up to~, as well as all pairwise nonisomorphic commutative, abelian, and rectangular doppelsemigroups of orders up to~, obtained using , , and .

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