We analyse physical and chemical structure of the hot molecular core RCW120 S2, based on high-sensitivity (2-4 mK) APEX observations at 1.3 mm. The analysis reveals a rich molecular inventory, including complex organic molecules (COMs) such as CHOH, CHCHO, CHOCHO and CHOCH. We derive gas temperatures (20-300 K), H densities (10-10cm), and molecular column densities. The detected emission probes a radially stratified envelope, with cooler (<= 60 K) and less dense (10-10cm) outer layers traced by SO, SO2, and c-CH, while warmer (60-100 K) and denser (10-10cm) inner regions are traced by HCO, OCS, and low-excitation CHCN. The hot gas (<= 100 K) exhibits broad (8-10 km/s) lines from high-excitation CHOH, CHCN, HDO, and CHOCH. Relative molecular abundances of COMs generally agree with astrochemical hot-core models, while methanol appears underabundant and CHCN overabundant compared to predictions. We attribute these discrepancies to the need for interferometric observations at intermediate spatial scales to resolve the core’s true filling factor and radial gradients.

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