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We prove the global-in-time existence of weak solutions for the Maxwell–Stefan–Fourier system with physically motivated degenerate thermal conductivity , for . In contrast to existing nonisothermal compressible theories based on nondegenerate conductivities, the entropy inequality no longer gives control of the quantities and . The main new ingredient is a renormalized energy estimate, which yields compactness of the temperature and allows the identification of the degenerate heat flux.

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