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The Migdal effect-the prompt ionization induced by a sudden nuclear recoil-is widely used in direct dark matter searches, yet its validity beyond the impulse approximation has remained unresolved. We present the first first-principles calculation for isolated atoms, establishing the adiabatic crossover where ionization is suppressed. We show that this behavior is fully encoded in the scattering amplitude, without ad hoc assumptions, and map the relevant parameter space, finding that dark matter searches lie in the unsuppressed regime.

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