The discovery of the hidden-charm pentaquarks , and by the LHCb collaboration are very likely to identify as the molecules. A natural and crucial extension is the existence of excited molecular partners built from a ground-state charmed baryon and a radially excited anti-charmed meson, namely molecules. In a framework of chiral quark model, we systematic study pion-emission decays of such excited molecules into the known ground-state molecules. Our results show that the decay widths are sensitive to the spin structures and the coupled-channel interferences, i.e., the state decays to with a width of several MeV, while the width to is suppressed below MeV due to destructive interference. The pion-emission decay can be the key to unveiling the excited molecular spectrum of hidden-charm pentaquarks and provides decisive experimental signatures. We expect the future experiments such as the LHCb and PANDA can verify our predictions.

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