Compression and heat release interact intermittently in high-speed reacting shear layers, and whole-field averages can obscure their coupling. We examine this coupling in a supersonic reacting hydrogen–air temporal mixing layer using time-resolved mid-plane slices from a three-dimensional direct numerical simulation. A fixed dilatation threshold identifies connected compression events, and exothermic heat release and mixture-fraction-gradient activity are then conditioned on the evolving event population. The record separates into startup (), transition (), and developed () regimes, with the developed regime carrying the persistent compression–chemistry interaction. In this regime, compression appears as a population of intermittent events with no single structure dominating the field. Stronger exothermic response is associated with larger maximum-event area, larger event count, greater compression–heat-release overlap, and smaller distance from compression to the most exothermic regions. Scalar-gradient amplification peaks near zero lag relative to compression-area excursions, whereas the strongest exothermic response precedes peak compression coverage by . These results show that compression organizes chemistry most clearly through event population, overlap, proximity, and lag, providing an event-level description of compression–chemistry coupling in an open supersonic reacting shear layer.

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