We investigate an invisible lepton-flavor-violating scalar with exclusive couplings and study its resonant production via in fixed-target experiments. Since the effective center-of-mass energy is determined by the momentum of the initial-state bound electrons, atomic effects can significantly affect the resonance behavior. We therefore employ relativistic bound-state electron wave functions to calculate the production cross section and reveal a material-dependent broadening of the resonance lineshape. For the proposed HIAF experiment, fewer than one day of data taking ( MOT) can probe couplings at the level at 90% confidence level near resonance, demonstrating that high-intensity muon fixed-target experiments provide a powerful complementary probe of lepton-flavor violation.

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