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In this paper, a natural duality on the family of biperiodic Fibonacci words generated by the directive sequence . Both of and are related by the explicit morphism , , establishing a precise substitutional correspondence between them. We compute the exact letter frequencies, give a complete description of the return words for each letter, prove the existence of arbitrarily long palindromic prefixes, and determine the continued fraction expansion of the slope . These findings reveal that the apparent asymmetry in several invariants arises uniformly from the length-redistribution mechanism induced by the morphism .

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