In this work, we focus on the light vector meson leading-twist longitudinal distribution amplitudes (DAs) with . In order to obtain their accurate behaviors, a new scheme of QCD sum rule research with respect to DA suggested in 2021 by us is adopted. With an improved sum rule formula, the -moments up to tenth order are calculated. In which, , , , , and the corresponding Gegenbauer moments , , , at the scale , respectively. By fitting those with the least squares method, the behaviors of leading-twist longitudinal DAs for are determined. Further, we recalculate the transition form factors and branching ratio of the , semi-leptonic decay processes.

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