Let p be an odd prime, let n=(p−1)/2, and let χ=(p⋅), with χ(0)=0. For a∈Fp× define Da(x)=1≤i,j≤ndet(x+χ(i2−aj)),Da(0)(x)=0≤i,j≤ndet(x+χ(i2−aj)). We prove Da(0)=0⟺p≡3(mod4)andχ(an!)=1. For p≡3(mod4) we also give explicit Pfaffian-square factorizations of Da(x) and Da(0)(x). Let sp=(−1)⌊(p+1)/8⌋. If χ(an!)=1, then spDa(x)/x=spDa(0)(x) is a positive integer square. If χ(an!)=−1, then there is a positive integer σ such that spDa(x)=σ2(nx−1),spDa(0)(x)=−σ2(n+(2n+1)x). The case a=n! settles Sun’s Conjecture 4.1.