We study late-time identification of the Caputo order in a linear diffusion equation generated by a strictly positive self-adjoint operator with compact resolvent. For signed scalar observations satisfying , we show that, after eigenspace grouping, every nontrivial observation has a finite first nonzero resolvent moment . A uniform differentiated large-argument expansion of the Mittag-Leffler factor yields eventual strict monotonicity of on admissible intervals avoiding the zeros of , hence uniqueness from one sufficiently late scalar measurement. For two measurements, , giving a log-ratio estimator with asymptotic-bias and relative-noise error bounds. For bounded observations, ; for a finite rod, the leading point-sensor condition is . Counterexamples show the sharpness of the exclusions and noise interpretation.

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