The search for neutrinoless double electron capture () provides a sensitive probe of lepton-number violation and the Majorana nature of neutrinos. We investigate the decay of Ca using cryogenic detectors equipped with metallic magnetic calorimeters in the AMoRE-I experiment. The analysis is based on a physics dataset corresponding to a total exposure of 7.32 kgyr from thirteen CaMoO crystals. No significant excess is observed, and a lower limit on the half-life is obtained as yr at 90 confidence level. An improved sensitivity is expected for the upcoming AMoRE-II experiment. These results demonstrate the potential of CaMoO detectors to explore rare decay processes beyond the primary Mo search program.

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