We study the semiclassical distribution of resonances of a matrix Schrödinger operator, obtained as a reduction of an Hamiltonian when studying molecular predissociation models under the Born-Oppenheimer approximation. The energy considered is above the energy-level crossing of the two associated classical trajectories, and is respectively trapping and non-trapping for those trajectories. Under a condition between the contact order of the crossings and the vanishing order of the interaction term at the crossing points, we show that, asymptotically in the semiclassical limit , the imaginary part of the resonances is of size in the general case and shrinks to when both and are odd. We also compute the first term of the associated asymptotic expansions.

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