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We report systematic large-scale shell-model calculation for Po isotopes with 200 to 210. We have performed calculations using KHH7B interaction in the model space = 58-114 and = 100-164 around doubly-magic Pb. We allow valence neutrons to occupy in the , , , and orbitals, while two valence protons beyond are occupied in , and orbitals. The calculated energies and electromagnetic properties are compared with the available experimental data and predicted where experimental data are not available. We have also reported shell-model results for different isomeric states of these nuclei.

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