We introduce a family of SO()-symmetric spin chains which generalize the transverse-field Ising chain for . These spin chains are defined with Gamma matrices and can be exactly solved by mapping to species of itinerant Majorana fermions coupled to a static gauge field. Their phase diagrams include a critical point described by the conformal field theory as well as two distinct gapped phases. We show that one of the gapped phases is a trivial phase and the other realizes a symmetry-protected topological phase when . These two gapped phases are proved to be related to each other by a Kramers-Wannier duality. Furthermore, other elegant structures in the transverse-field Ising chain, such as the infinite-dimensional Onsager algebra, also carry over to our models.

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