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We describe transposed Poisson structures on the upper triangular matrix Lie algebra , , over a field of characteristic zero. We prove that, for , any such structure is either of Poisson type or the orthogonal sum of a fixed non-Poisson structure with a structure of Poisson type, and for , there is one more class of transposed Poisson structures on . We also show that, up to isomorphism, the full matrix Lie algebra admits only one non-trivial transposed Poisson structure, and it is of Poisson type.

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