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In the current research work, our basic objective is to investigate the stucture of Hom-associative trialgebras. Next, we build up one important class of Hom-associative trialgebras and provide properties of right, left and meddle operations in Hom-associative trialgebras. Furthermore, we describe the classification of -dimensional Hom-associative trialgebras for . Additionally, the properties of the Inner-derivations and centroids are identified and discussed. Eventually the Inner-derivations and centroids are computed.

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