Fast non-volatile electric control of antiferromagnetic states

Electrical manipulation of antiferromagnetic states, a cornerstone of antiferromagnetic spintronics, is a great challenge, requiring novel material platforms. Here we report the full control over antiferromagnetic states by voltage pulses in the insulating Co${}_3$O${}_4$ spinel. We show that the strong linear magnetoelectric effect emerging in its antiferromagnetic state is fully governed by the orientation of the Néel vector. As a unique feature of Co${}_3$O${}_4$, the magnetoelectric energy can easily overcome the weak magnetocrystalline anisotropy, thus, the Néel vector can be manipulated on demand, either rotated smoothly or reversed suddenly, by combined electric and magnetic fields. We succeed with switching between antiferromagnetic states of opposite Néel vectors by voltage pulses within a few microsecond in macroscopic volumes. These observations render quasi-cubic antiferromagnets, like Co${}_3$O${}_4$, an ideal platform for the ultrafast (pico- to nanosecond) manipulation of microscopic antiferromagnetic domains and may pave the way for the realization of antiferromagnetic spintronic devices.