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Let be a graph with loops obtained from a graph of order and loops at . In this paper, we establish a neccesary and sufficient condition on the bipartititeness of a connected graph and the spectrum Spec() and Spec(). We also prove that for every , when is bipartite. Moreover, we provide an identification of the spectrum of complete graphs and complete bipartite graphs with loops. We characterize any graphs with loops of order n whose eigenvalues are all positive or non-negative, and also any graphs with a few distinct eigenvalues. Finally, we provide some bounds related to .

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