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We study the G-instanton condition for a family of metric connections arisen from the characteristic connection, on -dimensional -step nilpotent Lie groups with left-invariant coclosed G-structures. According to the dimension of the commutator subgroup, we establish necessary and sufficient conditions for the connection to be an instanton, in terms of the torsion of the G-structure, the torsion of the connection and the Lie group structure.Moreover, we show that in our setup, G-instantons define a naturally reductive structure on the simply connected -step nilpotent Lie group with left-invariant Riemannian metric. Taking quotient by lattices, one obtains G-instantons on compact nilmanifolds.

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