We analysed spectroscopic data obtained with VLT-VIMOS for two multiple-cluster systems, PLCKG and PLCKG, discovered via their thermal Sunyaev-Zel’dovich signal by . Combining the Optical spectroscopy, for the redshift determination, and photometric data from galaxy surveys (SDSS, WISE, DESI), we were able to study the structure of the two multiple-cluster systems, to determine their nature and the properties of their member galaxies. We found that the two systems are populated mainly with passive galaxies and that PLCKG consists of a pair of clusters at redshift and a background isolated cluster at , whereas the system PLCKG is a chance association of three independent clusters at redshifts , , and . We also find evidence for remaining star formation activity in the highest-redshift cluster of PLCKG, at .

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