SN~2021aefx is a normal Type Ia Supernova (SN) with red excess emission over the first 2 days. We present detailed analysis of this SN using our high-cadence KMTNet multi-band photometry, spectroscopy, and publicly available data. We provide the first measurements of its epochs of explosion (MJD 59529.32 0.16) as well as first light'' (MJD 59529.85 $\pm$ 0.55) associated with the main ejecta ${\rm{^{56}Ni}}$ distribution. This places our first detection of SN 2021aefx at $\sim -$0.5 hours since first light’', indicating the presence of additional power sources. Our peak-spectrum confirms its Type Ia sub-classification as intermediate between Core-Normal and Broad-Line, and we estimate the ejecta mass to be 1.34 . The pre-peak spectral evolution identifies fast-expanding material reaching 40,000 km s (the fastest ever observed in Type Ia SNe) and at least two distinct homologously-expanding ejecta components: (1) a normal-velocity (12,400 km s) component consistent with the typical photospheric evolution of Chandrasekhar-mass ejecta; and (2) a high-velocity (23,500 km s) component visible during the first 3.6 days post-explosion, which locates the component within the outer 16% of the ejecta mass. Asymmetric, subsonic explosion processes producing a non-spherical photosphere provide an explanation for the simultaneous presence of the two components, as well as the red excess emission via a slight enrichment in the outer 0.5% of the ejecta mass. Our spectrum from 300 days post-peak advances the constraint against non-degenerate companions and further supports a near-Chandrasekhar-mass explosion origin. Off-center ignited delayed-detonations of Chandrasekhar-mass white dwarfs may be responsible for the observed features of SN 2021aefx in some normal Type Ia SNe.

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