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In this paper we solve two open problems in ergodic theory. We prove first that if a Doeblin function (a -function) satisfies then we have a unique Doeblin measure (-measure). This result indicates a possible phase transition in analogy with the long-range Ising model. Secondly, we provide an example of a Doeblin function with a unique Doeblin measure that is not weakly mixing, which implies that the sequence of iterates of the transfer operator does not converge, solving a well-known folklore problem in ergodic theory. Previously it was only known that uniqueness does not imply the Bernoulli property.

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