On the Inertial Rotational Brownian Motion of Arbitrarily Shaped Particles

This article reports the modeling of inertial rotational Brownian motion as an Ornstein-Uhlenbeck process evolving on the cotangent bundle of the rotation group, SO(3). The benefit of this approach and the use of a different parameterization of rotations allows the handling of particles with arbitrary shapes, without requiring any simplifying assumptions on the shape or the structure of the viscosity tensors. The resultant Fokker-Planck equation for the joint orientation and angular momentum probability distribution can be solved approximately using an `ansatz’ Gaussian distribution in exponential coordinates.