Let , , be a sequence of finite sets and consider a -valued, irreducible, reversible, continuous-time Markov chain . Denote by the set of probability measures on and by the level two large deviations rate functional for as . We present a general method, based on tools used to prove the metastable behaviour of Markov chains, to derive a full expansion of expressing it as , where represent rate functionals independent of and sequences such that , for . The speed corresponds to the time-scale at which the Markov chains exhibits a metastable behavior, and the zero-level sets to the metastable states. To illustrate the theory we apply the method to random walks in potential fields.

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