We present a systematic small- expansion of the Liouville DOZZ three-point structure constant in the light-operator regime as . In this limit, the exact DOZZ function factorizes into a prefactor {\cal P(b;σ_1,σ_2,σ_3) and a power series in : Using Thorn’s asymptotic expansion of the -function we derive closed-form expressions for the leading coefficients and show that each is a symmetric polynomial in the variables . Our expansion provides explicit perturbative corrections to the semiclassical Liouville three-point function and therefore supplies a practical tool for applications in celestial holography, in particular, for generating loop-level corrections to the tree-level three-gluon scattering amplitude. Finally, we formulate a perturbative Liouville program for celestial amplitudes and outline directions for further development.

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