A fundamental question in the physics of droplet–fiber interactions is: What is the maximum droplet volume a fiber can retain? While this problem has been studied for horizontal fibers and at the apex -shaped bent fibers, it remains less explored for V-shaped bent fibers, despite their demonstrated advantages in engineering applications such as fog harvesting. This work investigates the capability of V-shaped fibers in retaining droplets against gravity. An analytical model to predict the maximum droplet volume on V-shaped fibers is developed based on free energy analysis, and validated against experimental data from five liquid–fiber pairs. The dependence of the maximum droplet volume on can be reasonably captured by the function , where denotes the droplet’s off-axis angle. As increases from to , the maximum droplet volume slightly decreases before entering a broad transition region around –, and then increases at larger .

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