In this paper, we performed a spectro-polarimetric analysis of the transient NS-LMXB XTE J1701-462 using IXPE, NICER, and NuSTAR data during its 2022 outburst. We report the significant detection of energy-dependent polarization in the X-ray signal from the source on 2022 September 29 in the keV, keV and keV energy bands with a polarization degree of % (10.7), % (9.1) and % (12.6), respectively. The polarization angle in the overall keV band was found to be . The spectra were modelled using a combination of thermal emission from an accretion disc, Comptonized emission from a hot electron plasma (or corona) and a Gaussian line. From spectro-polarimetric analysis, the polarization degree due to the disc emission was found to have an upper limit of %, and that of the Comptonized emission was constrained at % (at the 3 level). The results suggest that the Comptonized component probably originates from a spreading-layer/boundary-layer above the neutron star surface. IXPE observation of the same source on 2022 October 8 does not show significant polarization which can be attributed to a weakening of the coronal Comptonized emission. The implication of these results are discussed.

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