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Proximity induced superconductivity with a clean interface has attracted much attention in recent years. We discuss how the commonly-employed electron tunneling approximation can be hybridized with first-principles calculation to achieve a quantitative characterization starting from the microscopic atomic structure. By using the graphene-Zn heterostructure as an example, we compare this approximated treatment to the full anisotropic Eliashberg formalism. Based on the calculation results, we discuss how superconductivity is affected by the interfacial environment.

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