By using the spectrum of the underlying symmetric diffusion operator, the convergence in -Wasserstein distance is characterized for the empirical measure of non-symmetric subordinated diffusion processes in an abstract framework. The main results are applied to the subordinations of several typical models, which include the (reflecting) diffusion processes on compact manifolds, the conditional diffusion processes, the Wright-Fisher diffusion process, and hypoelliptic diffusion processes on {\bf SU}(2). In particular, for the (reflecting) diffusion processes on a compact Riemannian manifold with invariant probability measure : (1) the sharp limit of is derived in for concrete which provides a precise characterization on the physical observation that a divergence-free perturbation accelerates the convergence in ; (2) the sharp convergence rates are presented for , where a critical phenomenon appears with the critical rate as .

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