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We find phase transitions and critical phenomena of the FRW (Friedmann-Robertson-Walker) universe in the framework of an effective scalar-tensor theory that belongs to the Horndeski class. We identify the thermodynamic pressure (generalized force) of the FRW universe in this theory with the work density of the perfect fluid, which is a natural definition directly read out from the first law of thermodynamics. We derive the thermodynamic equation of state for the FRW universe in this theory and make a thorough discussion of its - phase transitions and critical phenomena. We calculate the critical exponents, and show that they are the same with the mean field theory, and thus obey the scaling laws.

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