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A set-theoretical solution of the pentagon equation on a non-empty set is a function satisfying the relation , with , and , where is the flip map given by , for all . Writing a solution as , where is a map, for every , one has that is a semigroup. In this paper, we study idempotent solutions, i.e., , by showing that the idempotents of have a key role in such an investigation. In particular, we describe all such solutions on monoids having central idempotents. Moreover, we focus on idempotent solutions defined on monoids for which the map is a monoid homomorphism.

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