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In this paper, we establish the necessary and sufficient conditions for quasi-cyclic (QC) codes with index even to be symplectic self-orthogonal. Subsequently, we present the lower and upper bounds on the minimum symplectic distances of a class of -generator QC codes and their symplectic dual codes by decomposing code spaces. As an application, we construct numerous new binary symplectic self-orthogonal QC codes with excellent parameters, leading to record-breaking quantum error-correction codes.

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