The maximum mass of black holes formed in isolated binaries is determined by stellar winds and the interactions between the binary components. We consider for the first time fully self-consistent detailed stellar structure and binary evolution calculations in population-synthesis models and a new, qualitatively different picture emerges for the formation of black-hole binaries, compared to studies employing rapid population synthesis models. We find merging binary black holes can form with a non-negligible rate () at solar metallicity. Their progenitor stars with initial masses do not expand to supergiant radii, mostly avoiding significant dust-driven or luminous blue variable winds. Overall, the progenitor stars lose less mass in stellar winds, resulting in black holes as massive as , and, approximately half of them avoid a mass-transfer episode before forming the first-born black hole. Finally, binaries with initial periods of a few days, some of which may undergo episodes of Roche-lobe overflow mass transfer, result in mildly spinning first-born black holes, , assuming efficient angular-momentum transport.

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